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An interactive Rudolph diagram

The Rudolph diagram

This shows the relationship between closo-, nido- and arachno- cluster geometries with 4 to 12 cluster vertices. The arrows connect clusters with the same number of electron pairs for cluster bonding. The number of electron pairs is given by n + 1 where n is the number of atoms in the closo anion at the start of the arrow. Use the mouse to rotate the molecules. This page loads slowly – please be patient.

polyhedron

closo

nido

arachno

vertices

tetrahedron 4
trigonal bipyramid 5
octahedron 6
pentagonal bipyramid 7
dodecahedron 8
capped Archimedean antiprism 9
bicapped Archimedean antiprism 10
octadecahedron 11
icosahedron 12