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Refereed papers in primary journals

 

1. A pentuply-bridging thiocarbonyl group: X-ray crystal structure of a salt of the 1-thio-2-phenyl-1,2-dicarbadodecaborate (12) anion, [LH]+[S(Ph)C2B10H10]– (L = 1,8-N,N,N’,N’-tetramethylnaphthalene diamine)

 

         R. Coult, M. A. Fox, W.R. Gill, K. Wade and W. Clegg,

         Polyhedron, 1992, 11, 2717-2721.

 

2. C-arylation and C-heteroarylation of icosahedral carboranes via their copper(I) derivatives

 

         R. Coult, M. A. Fox, W.R. Gill, P.L. Herbertson, J.A.H. MacBride and K. Wade,

         J. Organomet. Chem., 1993, 462, 19-29.

 

3. X-ray structure and bonding of 1-phenylethynyl-2-phenyl-1,2-dicarbadodecaborane(12), [1-(PhC≡C)-2-Ph-1,2-C2B10H10], a model alkyne complex containing a rich variety of carbon-carbon bond types

 

         W. Clegg, R. Coult, M. A. Fox, W.R. Gill, J.A.H. MacBride and K. Wade,

         Polyhedron, 1993, 12, 2711-2717.

 

4. Proposed structure of the first hypho carbaborane, C3B4H12

 

         M. A. Fox, R. Greatrex, N.N. Greenwood and M. Kirk,

         Polyhedron, 1993, 12, 1849-1853.

 

5. Even more reliable NMR chemical shift computations by the GIAO-MP2 method

 

         P.v.R. Schleyer, J. Gauss, M. Bühl, R. Greatrex and M. A. Fox,

         J. Chem. Soc., Chem. Commun., 1993, 1766-1768.

 

 

6. The true identity of the ‘bare-carbon’ cluster, closo-C3B5H7

 

         M. A. Fox and R. Greatrex,

         J. Chem. Soc., Dalton Trans., 1994, 3197-3198.

 

7. The structures of alkyl derivatives of arachno-1-CB4H10 from reactions of B4H10 with alkynes

 

         M. A. Fox, R. Greatrex, M. Hofmann and P.v.R. Schleyer,

         Angew. Chem. Int. Ed. Engl., 1994, 33, 2298-2300.

 

8. Re-identification of the major volatile carbaboranes from the gas-phase reactions of tetraborane(10) and alkynes at 50ºC

 

         M. A. Fox and R. Greatrex,

         J. Chem. Soc., Chem. Commun., 1995, 667-668.

 

9. 2,4-Ethanotetraborane derivatives. 2. Synthesis, characterization and gas-phase structures of 2,4-(MeCHCH2)B4H8, 2,4-(trans–MeCHCHMe)B4H8 and 2- and 4- Pr-2,4-(MeCHCH2)B4H7

 

         P.T. Brain, M. Bühl, M. A. Fox, R. Greatrex, E. Leuschner, M.J. Picton, D.W.H. Rankin and H.E. Robertson,

         Inorg. Chem., 1995, 34, 2841-2849.

 

10. Deboronation of C-substituted ortho– and meta–closo–carboranes using “wet” fluoride ion solutions.

 

         M. A. Fox, W.R. Gill, P.L. Herbertson, J.A.H. MacBride, K. Wade and H.M. Colquhoun,

         Polyhedron, 1996, 15, 565-571.

        

11. Gas-phase reactions of tetraborane(10) with 1-en-3-ynes: syntheses of the parent tricarbahexaborane, nido-2,3,4-C3B3H7 and its derivatives

 

         M. A. Fox, R. Greatrex and A. Nikrahi,

         Chem. Commun., 1996, 175-176.

 

12. Existence of C,3-Me2–closo-1,2-C2B3H3 refuted by the ab initio/IGLO, GIAO-MP2/NMR method. Attempted repetition of the synthesis

 

         M. Hofmann, M. A. Fox, R. Greatrex, P.v.R. Schleyer, J. W. Bausch and R.E. Williams,

         Inorg. Chem., 1996, 35, 6170-6178.

 

13. Crystallographic evidence for the diene character of C2B10H10C4H4 (‘benzocarborane’) and a Diels-Alder reaction of its anionic nido-analogue, [C2B9H10C4H4]–: crystal structures of C2B10H10C4H4 and C2B10H10C4H6.

 

         R.C.B. Copley, M. A. Fox, W.R. Gill, J.A.K. Howard, J.A.H. MacBride, R.J. Peace, G.P. Rivers and K. Wade,

         Chem. Commun., 1996, 2033-2034.

 

14. Fluoride-ion deboronation of p–fluorophenyl–ortho– and –meta–carboranes. NMR evidence for the new fluoroborate, HOBHF2–.

 

         M. A. Fox, J.A.H. MacBride and K. Wade,

         Polyhedron, 1997, 16, 2499-2507.

 

15. Gas-phase reaction of tetraborane(10) with allene: the fluxional arachno-1-carbapentaborane isomeric system and derivatives 1,2- and 1,3-Me2-1-CB4H8; analogies in 1-CB4H10, MeB5H10 and B5H10–.

 

         M. A. Fox, R. Greatrex, M. Hofmann, P.v.R. Schleyer and R.E. Williams,

         Angew. Chem. Int. Ed. Engl., 1997, 36, 1498-1500.

        

16. Molecular structure of trifluorophosphine tetraborane(8), B4H8PF3, as determined in the gas phase by electron diffraction and ab initio computations

 

         P.T. Brain, D.W.H. Rankin, H.E. Robertson, M. A. Fox, R. Greatrex, A. Nikrahi and M. Bühl,

         Inorg. Chem., 1997, 36, 1048-1054.

 

17. Cage-fluorination during deboronation of meta–carboranes

 

         M. A. Fox and K. Wade,

         Polyhedron, 1997, 16, 2517-2525.

 

18. Convenient direct syntheses of novel fused-ring CB4N5 systems by nitrile hydroboration

 

         R. Coult, M. A. Fox, B. Rand, K. Wade and A.V.K. Westwood,

         J. Chem. Soc., Dalton Trans., 1997, 3411-3413.

 

19. Some boron-containing ring systems

 

        K. Wade, M.G. Davidson, M. A. Fox, W.R. Gill, T.G. Hibbert and J.A.H. MacBride, Phosphorus, Sulfur and Silicon, 1997, 125,

         73-82.

 

20. 2,4-Ethanotetraborane derivatives. 3. Determination of the molecular structure of 2,4-(t-butylethano)tetraborane(10), 2,4-(ButCHCH2)B4H8, in the gas phase by electron diffraction

 

          P.T. Brain, M. Bühl, M. A. Fox, R. Greatrex, D. Hnyk, A. Nikrahi, D.W.H. Rankin and H.E. Robertson,

         J. Mol. Struct., 1998, 445, 319-334.

 

21. Studies on tetraborane(8) carbonyl, B4H8.CO: its isomeric composition in the gas phase and in solution, and its reactions with alkenes

 

         S.J. Cranson, M. A. Fox, R. Greatrex and N.N. Greenwood,

         J. Organomet. Chem., 1998, 550, 207-212.

 

22. Six-vertex nido-carborane structures with unusual CHB bridges or endo-CH hydrogens

 

         M. Hofmann, M. A. Fox, R. Greatrex, P.v.R. Schleyer and R.E. Williams,

         J. Organomet. Chem., 1998, 550, 331-340.

        

23. Gas-phase reaction of tetraborane(10) and ethyne: Molecular structure of nido-1,2-C2B3H7 in the gas phase.

 

         M. A. Fox, R. Greatrex, A. Nikrahi, P.T. Brain, M.J. Picton, D.W.H. Rankin, H.E. Robertson, M. Bühl, L. Li and R.A. Beaudet,

         Inorg. Chem., 1998, 37, 2166-2176.

 

24. Transmission of electronic effects by icosahedral carboranes; skeletal 13C chemical shifts and ultraviolet – visible spectra of substituted aryl-para–carboranes.

 

         M. A. Fox, R.J. Peace, J.A.H. MacBride and K. Wade,

         J. Chem. Soc., Dalton Trans., 1998, 401-411.

 

25. Molecular structures of 1,12-B12H10(CO)2 and its dihydrate 1,12-B12H10[C(OH)2]2 – a novel bis-carbene complex.

 

         M. A. Fox, J.A.K. Howard, J.M. Moloney and K. Wade,

         Chem. Commun., 1998, 2487-2488.

 

26. Deboronation of 9-substituted-ortho– and –meta–carboranes

 

         M. A. Fox and K. Wade,

         J. Organomet. Chem., 1999, 573, 279-291.

        

27. Gas-phase flash reactions of diborane, triborane carbonyl and tetraborane with alkynes

 

         M. A. Fox, R. Greatrex, N.N. Greenwood and M. Kirk,

         Coll. Czech. Chem. Commun., 1999, 64, 806-818.

 

28. Deboronation of ortho-carborane by an iminophosphorane: crystal structures of the novel carborane adduct nido–C2B10H12.HNP(NMe2)3 and the borenium salt [(Me2N)3PNHBNP(NMe2)3]2O2+(C2B9H12–)2

 

         M.G. Davidson, M. A. Fox, T.G. Hibbert, J.A.K. Howard, A. Mackinnon, I.S. Neretin and K. Wade,

         Chem. Commun., 1999, 1649-1650.

        

29. Syntheses and reactions of some new C-pentafluorophenyl and tetrafluorophenylene carborane systems

 

         A.S. Batsanov, M. A. Fox, J.A.K. Howard and K. Wade,

         J. Organomet. Chem., 2000, 597, 157-163.

 

30. 1,2-Ph2-9-I-1,2-closo-C2B10H9

 

         T.D. McGrath, M. A. Fox and A.J. Welch,

         Acta Cryst. C, 2000, C56, 487-488.

 

31. Synthesis and structure of 1,12-diethynyl-para-carborane

 

         A.S. Batsanov, M. A. Fox, J.A.K. Howard, J.A.H. MacBride and K. Wade,

         J. Organomet. Chem., 2000, 610, 20-24.

 

32. First structural characterization of a 2,1,12-MC2B9 metallacarborane, [2,2,2-(NMe2)3–closo-2,1,12-TaC2B9H11]. Trends in boron NMR shifts on replacing a {BH} vertex with a metal {MLn} vertex in icosahedral carboranes

 

         A.S. Batsanov, P.A. Eva, M. A. Fox, J.A.K. Howard, A.K. Hughes, A.L. Johnson, A.M. Martin and K. Wade,

         J. Chem. Soc., Dalton Trans., 2000, 3519-3525.

 

33. Why are B2O2 rings rare?

 

         J.M. Burke, M. A. Fox, A.E. Goeta, A.K. Hughes and T.B. Marder,

         Chem. Commun., 2000, 2217-2218.

 

34. Gas-phase reactions of nido-1-methylpentaborane with propyne and 2-pentyne. Formation of B-alkyl nido and closo carbaboranes.

 

         M. A. Fox, R. Greatrex, M. Hofmann and P.v.R. Schleyer,

         J. Organomet. Chem., 2000, 614–615, 262-268.

 

35. The molecular structure of (PSH+)(nido-7,8-C2B9H12–) determined by neutron diffraction (PS = proton sponge, 1,8-bis(dimethylamino)naphthalene)

 

         M. A. Fox, A.E. Goeta, J.A.K. Howard, A.K. Hughes, A.L. Johnson, D.A. Keen, K. Wade and C.C. Wilson,

         Inorg. Chem., 2001, 40, 173-175.

        

36. Empirical and ab Initio Energy/Architectural Patterns for 73 nido-6<V>-Carborane Isomers, from B6H9– to C4B2H6

 

         M. Hofmann, M. A. Fox, R. Greatrex, P. v. R. Schleyer, and R. E. Williams,

         Inorg. Chem., 2001, 40, 1790-1801.

 

37. Phosphine promoted substituent redistribution reactions of B-chlorocatechol borane: Molecular structures of ClBcat, BrBcat and L·ClBcat (cat=1,2-O2C6H4; L = PMe3, PEt3, PBu3t, PCy3, NEt3)

 

         R.B. Coapes, F.E.S. Souza, M. A. Fox, A.S. Batsanov, A.E. Goeta, D.S. Yufit, M.A. Leech, J.A.K. Howard, A.J. Scott, W. Clegg and T.B. Marder,

         J. Chem. Soc., Dalton Trans., 2001, 1201-1209.

 

38. Syntheses of B-methylated tantalum carboranes, (Me2N)3TaC2B9H10Me

 

         M. A. Fox, J.A.K. Howard, A.K. Hughes, J.M. Malget and D. S. Yufit,

         J. Chem. Soc., Dalton Trans., 2001, 2263-2269.

 

39. Electrochemical evidence for electronic interactions through the para-carborane skeleton in the novel tricluster [{Co2(CO)4(dppm)2}(μ-Me3SiC2CB10H10CC2SiMe3)]

 

         M. A. Fox, M.A.J. Paterson, C. Nervi, F. Galeotti, H. Puschmann, J.A.K. Howard and P.J. Low,

         Chem. Commun. 2001, 1610-1611.

 

40. Model compounds and monomers for phenylene ether carboranylene ketone (PECK) polymer synthesis: preparation and characterization of boron-arylated ortho carboranes bearing carboxyphenyl, phenoxyphenyl or benzoylphenyl substituents

 

         M. A. Fox and K. Wade,

         J. Mater. Chem., 2002, 12, 1301-1306.

 

41. Do the discrete dianions C2B9H112- exist? Characterisation of alkali metal salts of the 11-vertex nido dicarboranes, C2B9H112-, in solution

 

         M. A. Fox, A.K. Hughes, A.L. Johnson and M.A.J. Paterson,

         J. Chem. Soc., Dalton Trans., 2002, 2009-2019.

 

42. Synthesis of a New Boron Carbonitride with a B4C-Like Structure from the Thermolysis of N-Alkylated Borazines

 

         R. Brydson, H. Daniels, M. A. Fox, R. Greatrex and C. Workman,

         Chem. Commun., 2002, 718-719.

        

43. Crystal and molecular structures of the nido-carborane anions, 7,9– and 2,9-C2B9H12–

 

         M. A. Fox, A.E. Goeta, A.K. Hughes and A.L. Johnson,

         J. Chem. Soc., Dalton Trans., 2002, 2132-2141.

 

44. Halogenation of tris(amido)tantalacarboranes with dihalomethanes CH2X2 (X = Cl, Br)

 

         M. A. Fox, A. E. Goeta, A. K. Hughes, J. M. Malget and K. Wade,

         Coll. Czech. Chem. Commun., 2002, 67, 791-807.

 

45. A Convenient Cyanide-free “One-Pot” Synthesis of nido-Me3N-7-CB10H12 and nido-7-CB10H13–

 

         A. S. Batsanov, M. A. Fox, A. E. Goeta, J. A. K. Howard, A. K. Hughes and J. M. Malget,

         J. Chem. Soc., Dalton Trans., 2002, 2624-2631.

 

46. A new nido-5-vertex cluster, phosphacarba-nido-pentaborane, 2-tBu-1,2-PCB3H5

 

         P. N. Condick, M. A. Fox, R. Greatrex, C. Jones and D. L. Ormsby,

         Chem. Commun., 2002, 1448-1449.

 

47. Unexpected formation of new fluoroboranes from the reaction of NMe4B3H8 with BF3 and MeC≡CH; exo-2-FB4H9 and trans–MeCH=CHBF2

 

         M. A. Fox, R. Greatrex and D. L. Ormsby,

         Chem. Commun., 2002, 2052-2053.

 

48. Cage-closing reactions of the nido-carborane anion 7,9-C2B9H12– and derivatives; formation of neutral 11-vertex carboranes by acidification

 

         M. A. Fox, A. K. Hughes and J. M. Malget,

         J. Chem. Soc., Dalton Trans., 2002, 3505-3517.

 

49. Solution and Solid State Structure of the Anion [Ag2{closo-CB11H12}4]2–

 

         M. A. Fox, M.F. Mahon, N.J. Patmore and A.S. Weller,

         Inorg. Chem., 2002, 41, 4567-4573.

 

50. Carbon-boron-nitrogen alloys from borazarene-derived mesophase pitches

 

         A.V.K. Westwood, R. Brydson, R. Coult, M. A. Fox, B. Rand and K. Wade,

         Carbon, 2002, 40, 2157-2167.

.

51. 9,12-diiodo-1,2-dicarba-closo-dodecaborane(12)

 

         A.S. Batsanov, M. A. Fox, J.A.K. Howard, A.K. Hughes, A.L. Johnson and S.J. Martindale,

         Acta Cryst. C, 2003, 59, o74-o76.

 

52. Intra– and inter-molecular carboranyl C-H···N hydrogen bonds in pyridyl-containing ortho-carboranes

 

         E.S. Alekseyeva, A.S. Batsanov, L.A. Boyd, M. A. Fox, T.G. Hibbert, J.A.K. Howard, J.A.H. MacBride, A. Mackinnon and K. Wade,

         Dalton Trans., 2003, 475-482.

.

53. Synthesis and crystal structure of an assembly of three ortho-carborane cages linked via para-phenylene units. Effect of aryl orientation on cage C-C bond lengths in C-aryl-ortho–carboranes

 

         E.S. Alekseyeva, M. A. Fox, J.A.K. Howard, J.A.H. MacBride and K. Wade,

         Appl. Organomet. Chem., 2003, 17, 499-508.

 

54. Evolving patterns in boron cluster chemistry: a reassessment of some old generalizations

 

         M. A. Fox and K. Wade,

         Pure Appl. Chem., 2003, 75, 1315-1324.

 

55. Big Macrocyclic Assemblies of Carboranes (Big MACs): Synthesis and Crystal Structure of a Macrocyclic Assembly of four Carboranes containing alternate ortho– and meta–Carborane Icosahedra linked by para-phenylene units

 

         M. A. Fox, J. A. K. Howard, J. A. H. MacBride, A. Mackinnon and K. Wade,

         J. Organomet. Chem., 2003, 680, 155-164.

 

56. Dimesitylborane Monomer-Dimer Equilibrium in Solution, and the Solid-State Structure of the Dimer by Single Crystal Neutron and X-Ray Diffraction

 

         C.D. Entwistle, T.B. Marder, P.S. Smith, J.A. K. Howard, M. A. Fox and S.A. Mason,

         J. Organomet. Chem., 2003, 680, 165-172.

 

57. Alkynyl Gold(1) rigid rod molecules from 1,12-Bis(ethynyl)-dicarba-closo-dodecaborane(12)

 

         J. Vicente, M-T. Chicote, M.M. Alvarez–Falcón, M. A. Fox and D. Bautista,

         Organometallics, 2003 22, 4792-4797.

 

58. Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar’), or 2,4-(CF3)2C6H3 (Ar”) ligands

 

         S.M. Cornet, K.B. Dillon, C.D. Entwistle, M.A. Fox, A.E. Goeta, H.P. Goodwin, T.B. Marder and A.L. Thompson,

         Dalton Trans., 2003, 4395-4405.

 

59. The Synthesis and Molecular and Crystal Structures of 1-Methyl-2-carboxy-1,2-dicarba-closo-dodecaborane(12), 1-Phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane(12) and 1-Phenyl-2-benzoyl-1,2-dicarba-closo-dodecaborane(12)

 

         U. Venkatasubramanian, D.J. Donohoe, D. Ellis, B.T. Giles, S.A. Macgregor, S. Robertson, G.M. Rosair, A.J. Welch, A.S. Batsanov, L.A. Boyd, R.C.B. Copley, M.A. Fox, J.A.K. Howard and K. Wade,

         Polyhedron, 2004, 23, 629-636.

.

60. Gas-phase electron diffraction studies on two 11-vertex dicarbaboranes, closo-2,3-C2B9H11 and nido-2,9-C2B9H13

 

         I.D. Mackie, H.E. Robertson, D.W.H. Rankin, M.A. Fox and J.M. Malget,

         Inorg. Chem., 2004, 43, 5387-5392.

 

61. Exo–pi-bonding to an ortho-carborane hypercarbon atom: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy– and amino-carboranes, 1-X-2-Ph-1,2-C2B10H10 (X = F, OH or NH2) and related anions

 

         L.A. Boyd, W. Clegg, R.C.B. Copley, M.G. Davidson, M.A. Fox, T.G. Hibbert, J.A.K. Howard, A. Mackinnon, R.J. Peace and K. Wade,

         Dalton Trans., 2004, 2786-2799.

 

62. Two contrasting ethynyl hydroboration pathways in the formation of a novel tris-hydroboration product from reaction of dimesitylborane with 2,5-diethynylpyridine

 

         C.D. Entwistle, A.S. Batsanov, J.A.K. Howard, M.A. Fox and T.B. Marder,

         Chem. Commun., 2004, 702-703.

 

63. Cage C-H ∙∙X interactions in solid-state structures of icosahedral carboranes

 

         M.A. Fox and A.K. Hughes,

         Coord. Chem. Rev., 2004, 248, 457-476.

 

64. Sulfur, tin and gold derivatives of 1-(2’-pyridyl)-ortho-carborane, 1-R-2-X-1,2-C2B10H10 (R = 2’-pyridyl, X = SH, SnMe3 or AuPPh3)

 

         A. S. Batsanov, M. A. Fox, T. G. Hibbert, J. A. K. Howard, R. Kivekäs, A. Laromaine, R. Sillanpää, C. Viñas and K. Wade,

         Dalton Trans., 2004, 3822-3828.

 

65. Elemental Fluorine. Part 16. Versatile thin-film gas-liquid multi-channel microreactors for effective scale-out

 

         R.D. Chambers, M. A. Fox, D. Holling, T. Nakano, T. Okazoe and G. Sandford,

         Lab. Chip, 2005, 5, 191-198.

 

66.  Versatile gas/liquid microreactors for industry

 

         R.D. Chambers, M. A. Fox, D. Holling, T. Nakano, T. Okazoe and G. Sandford,

         Chem. Eng. Tech., 2005, 28, 344-352.

 

67. Elemental Fluorine. Part 18. Selective direct fluorination of 1,3-ketoesters and 1,3-diketones using gas/liquid microreactor technology

 

         R.D. Chambers, M. A. Fox and G. Sandford,

         Lab. Chip, 2005, 5, 1132-1139.

 

68. Gas-phase electron diffraction studies of the icosahedral carbaboranes, ortho-, meta– and para-C2B10H12

 

         A.R. Turner, H.E. Robertson, K.B. Borisenko, D.W.H. Rankin and M. A. Fox,

         Dalton Trans., 2005, 1310-1318.

 

69. Electronic interactions in bridged bis(cluster) assemblies – a comparison of para-CB10H10C, para-C6H4 and C4 bridges

 

         B. Le Guennic, K. Costuas, J.F. Halet, C. Nervi, M.A.J. Paterson, M. A. Fox, R.L. Roberts, D. Albesa-Jove, H. Puschmann,    J.A.K. Howard and P.J. Low,

         Comptes Rendus Chimie, 2005, 8, 1883-1896.

 

70. Reactions of icosahedral carboranes with iminotris(dimethylamino)phosphorane HNP(NMe2)3: a deboronation intermediate nido-C2B10H12.N(H)P(NMe2)3, deboronation reactions and hydrogen-bonded closo-carborane systems

 

         A. S. Batsanov, R.C.B. Copley, M.G. Davidson, M. A. Fox, T.G. Hibbert, J.A.K. Howard and K. Wade,

         J. Cluster Sci., 2006, 17, 119-137.

 

71. Preparative and structural studies on sulfur-linked carborane icosahedra: 2-Phenyl-ortho-carboranyl-sulfur systems (2-Ph-1,2-C2B10H10)2X (X= S, S2 or SO), and ortho-carborane-di-yl systems (1,2-C2B10H10Y)2 (Y= S or SO)

 

         A.S. Batsanov, W. Clegg, R.C.B. Copley, M.A. Fox, W.R. Gill, R.S. Grimditch, T.G. Hibbert, J.A.K. Howard, J.A.H. MacBride and K. Wade,

         Polyhedron 2006, 25, 300-306.

 

72. Synthetic and Structural Studies on C-Ethynyl– and C-Bromo–Carboranes. Gas Phase Electron Diffraction Studies of C-Ethynyl– and C-Trimethylsilylethynyl–para–carboranes

 

         M. A. Fox, A.M. Cameron, P.J. Low, M.A.J. Paterson, A.S. Batsanov, A.E. Goeta, D.W.H. Rankin, H.E. Robertson and J.T. Schirlin,

         Dalton Trans., 2006, 3544-3560. 

 

73. Improved syntheses of bis(ethynyl)-para-carboranes, 1,12-(RC≡C)2-1,12-C2B10H10 and 1,10-(RC≡C)2-1,10-C2B8H8 (R = H or Me3Si)

 

         M.A. Fox, T.E. Baines, D. Albesa-Jové, J.A.K. Howard and P.J. Low,

         J. Organomet. Chem., 2006, 691, 3889-3894.

 

74. Elemental Fluorine. Part 20. Selective direct fluorination of aromatics using gas/liquid microreactor technology

         R.D. Chambers, M. A. Fox, G. Sandford, J. Trmcic and A. Goeta,

         J. Fluorine Chem., 2007, 128, 29-33.

 

75. Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n+3 skeletal electron count

 

         M. A. Fox, C. Nervi, A. Crivello and P.J. Low,

         Chem. Commun., 2007, 2372-2374.

 

76. Spectroscopic properties and electronic structures of 17-electron half-sandwich ruthenium acetylide complexes, [Ru(CCAr)(L2)Cp ‘]+ (Ar = phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2 = (PPh3)2, Cp’ = Cp; L2 = dppe; Cp’ = Cp*)

 

         M.A. Fox, R.L. Roberts, W.M. Khairul, F. Hartl and P.J. Low,

         J. Organomet. Chem., 2007, 692, 3277-3290.

 

77. The preparation and characterisation of ruthenium cyanovinylidene complexes

 

         N.J. Brown, P.K. Eckert, M.A. Fox, D.S. Yufit, J.A.K. Howard and P.J. Low,

         Dalton Trans., 2008, 433-436.

 

78. Quenched gas-phase reactions of tetraborane(10), B4H10, with substituted alkynes: new nido-dicarbapentaboranes and arachno-monocarbapentaboranes

 

         M. A. Fox, R. Greatrex and A. Nikrahi,

         Dalton Trans., 2008, 676-684.

 

79. N–Phosphino–amidines and –guanidines: synthesis, structure and P,N–chelate chemistry

 

         L. Baiget, A. S. Batsanov, P. W. Dyer, M. A. Fox, M. J. Hanton, J. A. K. Howard, P. K. Lane, and S. Solomon,

         Dalton Trans., 2008, 1043-1056.

 

80. Ruthenium Complexes of C,C’-Bis(ethynyl)carboranes: An Investigation of Electronic Interactions Mediated by Spherical Pseudo-aromatic Spacers

 

         M. A. Fox, R. L. Roberts, T. E. Baines, B. Le Guennic, J.-F. Halet, F. Hartl, D. S. Yufit, D. Albesa-Jové, J. A. K. Howard and P. J. Low,

         J. Am. Chem. Soc., 2008, 130, 3566-3578.

 

81. Some transition metal complexes derived from mono- and di-ethynyl perfluorobenzenes.

 

         D.J. Armitt, M.I. Bruce, M. Gaudio, N.N. Zaitseva, B.W. Skelton, A.H. White, B. Le Guennic, J.-F. Halet, M.A. Fox, R.L. Roberts, F. Hartl and P.J. Low,

         Dalton Trans., 2008, 6763-6775.

 

 

82. Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex.

 

         M.E. Smith, E.L. Flynn, M.A. Fox, A. Trottier, E. Wrede, D.S. Yufit, J.A.K. Howard, K.L. Ronayne, M. Towrie, A.W. Parker, F. Hartl and P.J. Low,

         Chem. Commun., 2008, 5845-5847.

 

 

83. Structural, Spectroscopic, Electrochemical and Computational Studies of C,C’-diaryl-ortho-carboranes, 1-(4-XC6H4)-2-Ph-1,2-C2B10H10 (X = H, F, OMe, NMe2, NH2, OH and O–).

 

         M.A. Fox, C. Nervi, A. Crivello, A.S. Batsanov, J.A.K. Howard, K. Wade and P.J. Low,

         J. Solid State Electrochem., 2009, 13, 1483-1495.

 

84. DFT Studies of the σ-Donor/π-Acceptor Properties of [SnCB10H11]– and its Relationship to [SnCl3]–, CO, PF3, [SnB11H11]2-, SnC2B9H11 and Related SnC2BnHn+2 Compounds.

 

         M.A. Fox, T.B. Marder and L. Wesemann,

         Can. J. Chem., 2009, 87, 63-71.

 

85. Convenient preparation of transition metal alkynyl complexes by transmetallation from alkynyl–gold(I) precursors, Au(PPh3)(C≡CAr) (Ar = C6H5 or C6H4Me-4).

         W.M. Khairul,  M.A. Fox,  N. N. Zaitseva,  M. Gaudio,  D.S. Yufit,  B.W. Skelton,  A.H. White,  J.A.K. Howard,  M.I.  Bruce and P.J. Low,

         Dalton Trans., 2009, 610-620.

 

86. Experimental and computed dipole moments in donor-bridge-acceptor systems with p-phenylene and p-carboranediyl bridges.

 

         L. Drož, M.A. Fox, D. Hnyk, P.J. Low, J.A.H. MacBride and V. Všetečka,

         Coll. Czech. Chem. Commun., 2009, 74, 131-146.

 

87. Synthetic, structural, photophysical and computational studies of π-conjugated bis– and tris-1,3,2-diazaboroles and related bis(boryl) dithiophenes.

 

         L. Weber, V. Werner, M.A. Fox, T.B. Marder, S. Schwedler, A. Brockhinke, H.-G. Stammler and B. Neumann,

         Dalton Trans., 2009, 1339-1351.

 

 

88. New synthetic and structural studies on nitroso-ortho-carboranes RCB10H10CNO and bis(ortho-carboranyl)amines (RCB10H10C)2NH (R = Ph or Me).

 

         M.A. Fox, J.A.H. MacBride, R.J. Peace, W. Clegg, M.R.J. Elsegood and K. Wade,

         Polyhedron., 2009, 28, 789-795.

 

89. Synthetic, Structural, Photophysical and Computational Studies on 2-Arylethynyl-1,3,2-Diazaboroles.

         L. Weber, V. Werner, M.A. Fox, T.B. Marder, S. Schwedler, A. Brockhinke, H.-G. Stammler and B. Neumann,

         Dalton Trans., 2009, 2823-2831.

 

90. Simple syntheses of trans–RuCl(C≡CR)(dppe)2 complexes and representative molecular structures.

         M.A. Fox,  J. E. Harris, S. Heider, V. Pérez-Gregorio, M. E. Zakrzewska, J. D. Farmer, D.S. Yufit,  J.A.K. Howard  and P.J. Low,

         J. Organomet. Chem., 2009, 694, 2350-2358.

 

91. Trends in ortho-carboranes 1-X-2-R-1,2-C2B10H10 (R = Ph or Me) bearing an exo-CN-bonded substituent group (X = NO, N=NR’ or NHR’’).

 

         M.A. Fox, R.J. Peace, W. Clegg, M.R.J. Elsegood and K. Wade,

         Polyhedron, 2009, 28, 2359-2370.

 

92. Noninnocent Ligand Behavior in Diruthenium Complexes Containing a 1,3-Diethynylbenzene Bridge.

 

         M.A. Fox, J.D. Farmer, R.L. Roberts, M.G. Humphrey and P.J. Low,

         Organometallics, 2009, 28, 5266-5269.

 

93. The syntheses and structures of mono- and di-bromovinylidenes.

 

         N.J. Brown, M.A. Fox, M.E. Smith, D.S. Yufit, J.A.K. Howard and P.J. Low,

         J. Organomet. Chem., 2009, 694, 4042-4048.

 

94. From Cyclic Iminophosphoranes to π-Conjugated Materials.

 

         D.A. Smith, A.S. Batsanov, M.A. Fox, A. Beeby, D.C. Apperley, J. A. K. Howard and P.W. Dyer,

         Angew. Chem. Int. Ed, 2009, 48, 9109-9113.

 

 

95. Luminescent Platinum(II) Complexes Containing Cyclometallated Diaryl Ketimine Ligands: Synthesis, Photophysical and Computational Properties.

 

         S.U. Pandya, K.C. Moss, M.R. Bryce, A.S. Batsanov, M.A. Fox, V. Jankus, H.A. Al-Attar and A.P. Monkman,

         Eur. J. Inorg. Chem., 2010, 1963-1972.

 

96. Syntheses and molecular structures of some tricobalt carbonyl clusters containing 2,4,6-trimethyl-1,3,5-trithiane.

 

         M.I. Bruce, N.N. Zaitseva, B.W. Skelton, A.H. White, M.A. Fox and P.J. Low,

         Dalton Trans., 2010, 39, 1222-1234.

 

 

97. Some reactions of an η3-tetracyanobutadienyl-ruthenium complex.

 

         M.I. Bruce, M.A. Fox, P.J. Low, B.W. Skelton and N.N. Zaitseva,

         Dalton Trans., 2010, 39, 3759-3770.

 

98. Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes.

 

         C.E. Willans, C.A. Kilner and M.A. Fox,

         Chem. Eur. J., 2010, 16, 10644-10648.

 

99. The electronic structures of di-ruthenium complexes containing an oligo(phenylene ethynylene) bridging ligand, and some related molecular structures.

 

         W.M. Khairul, M.A. Fox, P.A. Schauer, D.S. Yufit, D. Albesa-Jové, J.A.K. Howard and P.J. Low,

         Dalton Trans., 2010, in press.

 

100. Tuning the Intramolecular Charge-Transfer Emission from Deep Blue to Green in Ambipolar Systems Based on Dibenzothiophene–S,S-Dioxide by Manipulation of Conjugation and Strength of the Electron Donor Units.

 

         K.C. Moss,  K.N. Bourdakos, V. Bhalla, K.T. Kamtekar, M.R. Bryce, M.A. Fox, H.L. Vaughan, F.B. Dias and A.P. Monkman,

         J. Org. Chem., 2010, in press